The movement of a
system toward equilibrium will, under the proper circumstance, perform
work on an external system. Examples include economic expansion in one
sector upon organizations throughout the society; similarly for new
political, religious, and cultural ideologies. Thermodynamic power, as
a method of performing work on a system, is the consideration to which I
turn in this section.
In order to keep the
analysis simple and focused upon the essentials, I will idealize the
description of the external systems upon which work is performed. Since
these external systems are simply the recipient of work, the
idealization will not unduly affect the significance of the results.
I introduce the
following useful types of systems. The mathematical base for this is a
direct analogy with physical thermodynamics.
Definition:
An adiabatic barrier prevents the flow of heat flux.
Definition: A
reversible work source is a system enclosed by an adiabatic and
entity barrier characterized by relaxation times sufficiently short that
all processes of interest within it are essentially quasi-static.
Since the relationship
between quasi-static heat flux and entropy change can be represented by
dQ = Tds, the adiabatic barrier insures a constant value of entropy.
When coupled to another system, a reversible work source acts as a
quasi-static source or sink of work.
Definition: A
reversible heat source is a system contained in a rigid entity
relationship volume and characterized by relaxation times sufficiently
short that all processes of interest within it are essentially
quasi-static.
The only possible flux
of energy to or from a reversible heat source is in the form of heat, so
that dU = dQ = TdS. The reversible heat source acts as a quasi-static
source or sink of heat.
Definition: A
reservoir is a very large reversible work or heat source.
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(C) 2005-2014 Wayne M. Angel.
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